No, look that you cannot use \\ in function body. Elixir is capable of parsing a predefined set of operators. Some of them are macros, but some of them are used only within other macros (like defor defp) and because of that their AST representation is used instead.

(…) these operators appear in the precedence table above but are only meaningful within certain constructs:

• => - see %{}
• when - see Guards
• <- - see for and with
• \\ - see Default arguments

Source: Operators reference — Elixir v1.20.2

Take a look at a simplest example:

defmodule Example do
  defmacro sample({:\\, _, [left, right]}) do
    quote bind_quoted: [left: left, right: right] do
      if is_nil(left) do
        {:right, right}
      else
        {:left, left}
      end
    end
  end
end

iex> require Example
Example
iex> Example.sample(1 \\ 2)
{:left, 1}
iex> Example.sample(nil \\ 2)
{:right, 2}

Since \\ is a valid operator you are also able to define it, so it can be used inside function body:

defmodule Example do
  def left \\ right do
    {left, right}
  end
end

iex> import Example
Example
iex> 1 \\ 2  
{1, 2}